Heterogeneous Catalysis in Organic Chemistry

Book Description

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses.

Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry.

Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses.

Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search.

Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces.

Key Features
* Written by organic chemists for organic chemists
* Introduces heterogeneous catalysis concepts and language
* Presents a comprehensive compilation of protecting group removal procedures
* Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations
* Addresses heterogeneous methods for producing pure enantiomers of chiral products
* Examines the emerging field of heterogenized homogeneous catalysts
* Mixes practical applications with mechanistic interpretations

Customer Reviews:

Heterogeneous Hydrogenation Made Accesible.......2000-04-08

For the advanced organic chemistry researcher who is entering the wonderful world of heterogeneous catalysis in general - and heterogeneous hydrogenation in particular - there is no single resource such as this to guide him. Working in the field of heterogeneous hydrogenation myself, I had felt that a modern, up-to-date, readable text was long overdue. Heterogeneous Catalysis in Organic Chemistry has all of these attributes and much much more. It will help you o brave chemist to safely navigate the enormous and often useless primary literature and reach what you were looking for. Be that experimental details for a particular transformation, current developments in the scope of the field, understanding of the underlying theory. I strongly reccomend all organic synthesis research departments obtain a copy. It will be invaluable for the whole range of staff, from the first year inexperienced graduate student nervously exploring the field, to the research group leader who wants to update his knowledge and understanding, painlesly, accurately and quickly.

Metal Catalysed Reactions in Ionic Liquids (Catalysis by Metal Complexes)

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Metal Catalysed Reactions in Ionic Liquids (Catalysis by Metal Complexes)
Paul J. Dyson , and Tilmann J. Geldbach
Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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ASIN: 140203914X

Book Description

This book represents first non-edited book on the subject of metal catalysed reactions in ionic liquids and covers the literature from its origins until early 2005. Following a general introduction to the field of biphasic/mutliphasic catalysis, the synthesis, functionalisation and fundamental properties of ionic liquids relevant to catalysis are described. In the ensuing chapters catalysed reactions are discussed according to their type, encompassing hydrogenation, hydroformylation, oxidation, C-C coupling reactions, metathesis, dimerisation, polymerisation and more. Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are discussed. Specific processes such as supported ionic liquid phase catalysis, continuous processes using CO ₂ extraction and nanoparticle catalysis are covered. The book should be of interest to all those working in catalysis/green chemistry, in particular, to advanced level undergraduate and graduate students and all those researching or contemplating research in bi- or multiphasic catalysis using ionic liquids.

Metal-Catalysed Reactions of Hydrocarbons (Fundamental and Applied Catalysis)

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Metal-Catalysed Reactions of Hydrocarbons (Fundamental and Applied Catalysis)
Geoffrey C. Bond
Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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ASIN: 0387241418

Book Description

This unique book, drawing on the author’s lifetime experience, critically evaluates the extensive literature on the field of Metal-Catalysed Reactions of Hydrocarbons. Emphasis is placed on reaction mechanisms involving hydrogenation, hydrogenolysis, skeletal and positional isomerisation, and exchange reactions. The motivation for fundamental research in heterogeneous catalysis is to identify the physicochemical characteristics of active centres for the reaction being studied, to learn how these may be modified or manipulated to improve the desired behavior of the catalyst, and to recognize and control those aspects of the catalyst's structure that limit its overall performance. By restricting the subject of the book to hydrocarbons, Bond has progressively developed the subject matter to include areas of importance both to researchers and to those working in the industry.

Asymmetric Organocatalysis: From Biomimetic Concepts to Applications in Asymmetric Synthesis

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Asymmetric Organocatalysis: From Biomimetic Concepts to Applications in Asymmetric Synthesis
Albrecht Berkessel , and Harald Gröger
Manufacturer: Wiley-VCH
ProductGroup: Book
Binding: Hardcover

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ASIN: 3527305173

Book Description

Asymmetric catalysis represents still one of the major challenges in modern organic chemistry. Besides the well-established asymmetric metal-complex-catalysed syntheses and biocatalysis, the use of "pure" organic catalysts turned out to be an additional efficient tool for the synthesis of chiral building blocks. In this handbook, the experienced authors from academia and industry provide the first overview of the important use of such metal-free organic catalysts in organic chemistry. With its comprehensive description of numerous reaction types, e.g., nucleophilic substitution and addition reactions as well as cycloadditions and redox reactions, this book targets organic chemists working in industry and academia, and deserves a place in every laboratory.

Catalysis of Organic Reactions (Chemical Industries Series)

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Catalysis of Organic Reactions (Chemical Industries Series)

Manufacturer: CRC
ProductGroup: Book
Binding: Hardcover

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ASIN: 0849375576

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Bringing together academic, industrial, and governmental researchers and developers, Catalysis of Organic Reactions comprises 57 peer-reviewed papers on the latest scientific developments in applied catalysis for organic reactions. The volume describes the use of both heterogeneous and homogeneous catalyst systems and includes original research articles on processes with potential industrial applications. The contributors, renowned leaders in the field, discuss noteworthy findings that include the award-winning studies by Isamu Yamauchi on metastable precursors to Raney® catalysts and by Gadi Rothenberg on methods for finding the best homogeneous catalysts. The book covers the synthesis of fine chemicals and pharmaceutical intermediates, solid acid catalysis, selective oxidation, chiral synthesis, combinatorial methods, nanotechnology, and "green" processes. These topics are organized by broad groupings based on major process types, such as hydrogenations and oxidations, or themes, such as novel methods and environmental consciousness. Covering the most recent significant developments in catalysis, this compilation is ideal for chemists and chemical engineers who apply homogeneous and heterogeneous catalysis in the synthesis of pharmaceutical, fine, or commodity chemicals.

Metal-Catalysis in Industrial Organic Processes

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Metal-Catalysis in Industrial Organic Processes

Manufacturer: Royal Society of Chemistry
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Binding: Hardcover

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Book Description

Catalysis underpins most modern industrial organic processes. It has become an essential tool in creating a 'greener' chemical industry by replacing more traditional stoichiometric reactions, which have high energy consumption and high waste production, with mild processes which increasingly resemble Nature's enzymes.

Metal-Catalysis in Industrial Organic Processes considers the major areas of the field and discusses the logic of using catalysis in industrial processes. The book provides information on oxidation, hydrogenation, carbonylation, C-C bond formation, metathesis and polymerization processes, as well as on the mechanisms involved. In addition two appendices offer a concise treatment of homogeneous and heterogeneous catalysis. Numerous exercises referring to problems of catalytic processes, and research perspectives complete the book.

This definitive reference source, written by practising experts in the field, provides detailed and up-to-date information on key aspects of metal catalysis.

Catalytic Asymmetric Synthesis, Second Edition

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Catalytic Asymmetric Synthesis, Second Edition

Manufacturer: Wiley-VCH
ProductGroup: Book
Binding: Hardcover

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ASIN: 0471298050

Book Description

From the reviews of the First Edition . . .

"An excellent text . . . will no doubt provide the benchmark for comparative works for many years."
—Journal of the American Chemical Society

"A resounding success . . . the definitive current summaries on their respective subjects."
—Synthesis

Since this important work was first published in 1993, the field of catalytic asymmetric synthesis has grown explosively, spawning effective new methods for obtaining enantiomerically pure compounds on a large scale and stimulating new applications in diverse fields-from medicine to materials science. Catalytic Asymmetric Synthesis, Second Edition addresses these rapid changes through new or substantially revised contributions from highly recognized world leaders in the field. It presents detailed accounts of the most important catalytic asymmetric reactions known today, discusses recent advances, and retains from the previous edition essential and intriguing information on the initial development of certain processes. An excellent working resource for academic researchers and industrial chemists alike, the Second Edition features:

Contributions from Noyori, Sharpless, Kagan, Trost, Overman, Shibasaki, Doyle, Okamoto, Bolm, Carreira, and many other internationally renowned authorities
New chapters on asymmetric carbometallations, asymmetric amplification and autocatalysis, and asymmetric polymerization
Extended coverage of asymmetric carbene reactions, including asymmetric intramolecular carbene insertion to C-H bonds as well as asymmetric dihydroxylation and aminohydroxylation
Extended coverage of asymmetric carbon-carbon bond-forming reactions and applications
An appendix listing all chiral ligands in the book

Download Description

From the reviews of the First Edition . . .

"An excellent text . . . will no doubt provide the benchmark for comparative works for many years."-Journal of the American Chemical Society

"A resounding success . . . the definitive current summaries on their respective subjects."-Synthesis

Since this important work was first published in 1993, the field of catalytic asymmetric synthesis has grown explosively, spawning effective new methods for obtaining enantiomerically pure compounds on a large scale and stimulating new applications in diverse fields-from medicine to materials science. Catalytic Asymmetric Synthesis, Second Edition addresses these rapid changes through new or substantially revised contributions from highly recognized world leaders in the field. It presents detailed accounts of the most important catalytic asymmetric reactions known today, discusses recent advances, and retains from the previous edition essential and intriguing information on the initial development of certain processes. An excellent working resource for academic researchers and industrial chemists alike, the Second Edition features:
* Contributions from Noyori, Sharpless, Kagan, Trost, Overman, Shibasaki, Doyle, Okamoto, Bolm, Carreira, and many other internationally renowned authorities
* New chapters on asymmetric carbometallations, asymmetric amplification and autocatalysis, and asymmetric polymerization
* Extended coverage of asymmetric carbene reactions, including asymmetric intramolecular carbene insertion to C-H bonds as well as asymmetric dihydroxylation and aminohydroxylation
* Extended coverage of asymmetric carbon-carbon bond-forming reactions and applications
* An appendix listing all chiral ligands in the book

Acid Catalysis in Modern Organic Synthesis

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Acid Catalysis in Modern Organic Synthesis

Manufacturer: John Wiley & Sons
ProductGroup: Book
Binding: Hardcover

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ASIN: 3527317244

Book Description

This two-volume set covers all new developments and, in addition, includes the hot concept of combined Bronsted and Lewis acid catalysis, developed by Hisashi Yamamoto himself. The excellent editorial team has put together an equally top team of expert authors, resulting in a true treasure trove of essential information -- making this a must for every chemist working in organic chemistry and catalysis, in academia as well as in industry.

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY (and not medicine)

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Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes Category should be: CHEMISTRY (and not medicine)
A.E. Shilov , Georgiy B. Shul'pin , and Alexander E. Shilov
Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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Book Description

This monograph is devoted to the activation and various transformations of saturated hydrocarbons (alkanes), i.e. reactions accompanied by the C-H and C-C bond cleavage. Alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for the chemical industry. On the other hand, these substances are known to be the least reactive organic compounds. Special attention is paid to the recently found alkane activations in the presence of metal complexes, which are described in more detail. In addition to the reactions of saturated hydrocarbons which are the main topic of this book, the activation of C-H bonds in arenes and even olefins and acetylenes are considered. The monograph will be useful not only for those who are interested in the activation of alkanes and other hydrocarbons by metal complexes, but also for specialists in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. Some parts of the monograph will be of interest for specialists in inorganic and organic chemistry, theoretical chemistry, biochemistry and even biology, and also for those who work in the petrochemical industry, industrial organic synthesis and biotechnology.

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes (Catalysis by Metal Complexes)

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Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes (Catalysis by Metal Complexes)
A.E. Shilov , and Georgiy B. Shul'pin
Manufacturer: Springer
ProductGroup: Book
Binding: Paperback

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ASIN: 1402004206

Book Description

The transition from the Eocene to the Oligocene epoch, occurring approximately 47 to 30 million years ago, was the most dramatic episode of climatic and biotic change since the demise of the dinosaurs. The mild tropical climates of the Paleocene and early Eocene were replaced by modern climatic conditions and extremes, including glacial ice in Antarctica. The first part of this book summarizes the latest information in the dating and correlation of the strata of late middle Eocene through early Oligocene age in North America. The second part reviews almost all the important terrestrial reptiles and mammals found near the Eocene-Oligocene boundary, in the White River Chronofauna--from the turtles, snakes and lizards to the common rodents, carnivores, oreodonts and deer of the Badlands. This is the first comprehensive treatment of these topics in over sixty years, and will be invaluable to vertebrate paleontologists, geologists, mammalogists and evolutionary biologists.

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